50,533 research outputs found
Dielectric response effects in attosecond time-resolved streaked photoelectron spectra of metal surfaces
The release of conduction-band electrons from a metal surface by a
sub-femtosecond extreme ultraviolet (XUV) pulse, and their propagation through
the solid, provokes a dielectric response in the solid that acts back on the
photoelectron wave packet. We calculated the (wake) potential associated with
this photoelectron self-interaction in terms of bulk and surface plasmon
excitations and show that it induces a considerable, XUV-frequency-dependent
temporal shift in laser-streaked XUV photoemission spectra, suggesting the
observation of the ultrafast solid-state dielectric response in contemporary
streaked photoemission experiments.Comment: 4 pages and 4 figures, submitted to PR
Photon-Photon Interaction in a Photon Gas
Using the effective Lagrangian for the low energy photon-photon interaction
the lowest order photon self energy at finite temperature and in
non-equilibrium is calculated within the real time formalism. The Debye mass,
the dispersion relation, the dielectric tensor, and the velocity of light
following from the photon self energy are discussed. As an application we
consider the interaction of photons with the cosmic microwave background
radiation.Comment: REVTEX, 7 pages, 1 PostSrcipt figur
Resonance energy transfer from a fluorescent dye molecule to plasmon and electron-hole excitations of a metal nanoparticle
We study the distance dependence of the rate of electronic excitation energy
transfer from a dye molecule to a metal nanoparticle. Using the spherical
jellium model, we evaluate the rates corresponding to the excitation of l = 1,
2, and 3 modes of the nanoparticle. Our calculation takes into account both the
electron-hole pair and the plasmon excitations of the nanoparticle. The rate
follows conventional R^-6 dependence at large distances while small deviations
from this behavior are observed at shorter distances. Within the framework of
the jellium model, it is not possible to attribute the experimentally observed
d^-4 dependence of the rate to energy transfer to plasmons or e-h pair
excitations.Comment: 4 figure
Ethane steam reforming over a platinum/alumina catalyst: effect of sulphur poisoning
In this study we have examined the adsorption of hydrogen sulfide and methanethiol over platinum catalysts and examined the effect of these poisons on the steam reforming of ethane. Adsorption of hydrogen sulfide was measured at 293 and 873 K. At 873 K the adsorbed state of hydrogen sulfide in the presence of hydrogen was SH rather than S, even though the Pt:S ratio was unity. The effect of 11.2 ppm hydrogen sulfide or methanethiol on the steam reforming of ethane was studied at 873 K and 20 barg. Both poisons deactivated the catalyst over a number of hours, but methanethiol was found to be more deleterious, reducing the conversion by almost an order of magnitude, possibly due to the co-deposition of sulfur and carbon. Changes in the selectivity revealed that the effect of sulfur was not uniform on the reactions occurring, with the production of methane reduced proportionally more than the other products, due to the surface sensitivity of the hydrogenolysis and methanation reactions. The water-gas shift reaction was affected to a lesser extent. No regeneration was observed when hydrogen sulfide was removed from the feedstream in agreement with adsorption studies. A slight regeneration was observed when methanethiol was removed from the feed, but this was believed to be due to the removal of carbon rather than sulfur. The overall effect of sulfur poisoning was to reduce activity and enhance hydrogen selectivity
Biot-Savart-like law in electrostatics
The Biot-Savart law is a well-known and powerful theoretical tool used to
calculate magnetic fields due to currents in magnetostatics. We extend the
range of applicability and the formal structure of the Biot-Savart law to
electrostatics by deriving a Biot-Savart-like law suitable for calculating
electric fields. We show that, under certain circumstances, the traditional
Dirichlet problem can be mapped onto a much simpler Biot-Savart-like problem.
We find an integral expression for the electric field due to an arbitrarily
shaped, planar region kept at a fixed electric potential, in an otherwise
grounded plane. As a by-product we present a very simple formula to compute the
field produced in the plane defined by such a region. We illustrate the
usefulness of our approach by calculating the electric field produced by planar
regions of a few nontrivial shapes.Comment: 14 pages, 6 figures, RevTex, accepted for publication in the European
Journal of Physic
Can Maxwell's equations be obtained from the continuity equation?
We formulate an existence theorem that states that given localized scalar and
vector time-dependent sources satisfying the continuity equation, there exist
two retarded fields that satisfy a set of four field equations. If the theorem
is applied to the usual electromagnetic charge and current densities, the
retarded fields are identified with the electric and magnetic fields and the
associated field equations with Maxwell's equations. This application of the
theorem suggests that charge conservation can be considered to be the
fundamental assumption underlying Maxwell's equations.Comment: 14 pages. See the comment: "O. D. Jefimenko, Causal equations for
electric and magnetic fields and Maxwell's equations: comment on a paper by
Heras [Am. J. Phys. 76, 101 (2008)].
Relativistic three-body recombination with the QED vacuum
Electron-positron pair annihilation into a single photon is studied when a
second free electron is present. Focussing on the relativistic regime, we show
that the photon emitted in the three-lepton interaction may exhibit distinct
angular distributions and polarization properties. Moreover, the process can
dominate over two-photon annihilation in relativistic electron-positron plasmas
of few-MeV temperature. An analogy with three-body recombination of electrons
with ions is drawn.Comment: 5 pages, 4 figure
Disordered graphene and boron nitride in a microwave tight-binding analog
Experiments on hexagonal graphene-like structures using microwave measuring
techniques are presented. The lowest transverse-electric resonance of coupled
dielectric disks sandwiched between two metallic plates establishes a
tight-binding configuration. The nearest-neighbor coupling approximation is
investigated in systems with few disks. Taking advantage of the high
flexibility of the disks positions, consequences of the disorder introduced in
the graphene lattice on the Dirac points are investigated. Using two different
types of disks, a boron-nitride-like structure (a hexagonal lattice with a
two-atom basis) is implemented, showing the appearance of a band gap.Comment: 12 pages, 14 figure
Finding the way forward for forensic science in the US:a commentary on the PCAST report
A recent report by the US President’s Council of Advisors on Science and Technology (PCAST) [1] has made a number of recommendations for the future development of forensic science. Whereas we all agree that there is much need for change, we find that the PCAST report recommendations are founded on serious misunderstandings. We explain the traditional forensic paradigms of match and identification and the more recent foundation of the logical approach to evidence evaluation. This forms the groundwork for exposing many sources of confusion in the PCAST report. We explain how the notion of treating the scientist as a black box and the assignment of evidential weight through error rates is overly restrictive and misconceived. Our own view sees inferential logic, the development of calibrated knowledge and understanding of scientists as the core of the advance of the profession
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